Zinc Catalyzed Claisen Rearrangement of Allyl Aryl Ethers to o-Allylated Phenols in Liquid Phase~!2009-11-02~!2009-12-25~!2010-04-23~!

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منابع مشابه

Zinc Catalyzed Claisen Rearrangement of Allyl Aryl Ethers to o-Allylated Phenols in Liquid Phase

A simple and efficient method is developed for the zinc catalyzed Claisen rearrangement of allyl aryl ethers to o-allyl phenols by stirring in an oil-bath at 55 °C in liquid phase. Moreover, zinc powder is re-cyclable up to six times use without much loss of significant activity. In addition to it, the products are obtained in good to excellent yields and are in a state of high purity. The stru...

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Gold(I)-catalyzed formation of furans by a Claisen-type rearrangement of ynenyl allyl ethers

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Lewis Acid Mediated Claisen-Type Rearrangement of Aryl Dienyl Ethers

The Claisen rearrangement and its applications to organic synthesis have been studied for a long time.l In recent years, this rearrangement has been applied in stereocontrolled natural product synthesis2 and asymmetric i n d ~ c t i o n . ~ The term "Claisen rearrangement", which originally denoted the rearrangement of allyl aryl ethers to 0or p-allylphenols, has now been extended to analogous ...

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Gold(I)-catalyzed Claisen rearrangement of allenyl vinyl ethers; synthesis of substituted 1,3-dienes.

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Gold(I)-catalyzed propargyl Claisen rearrangement.

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ژورنال

عنوان ژورنال: The Open Catalysis Journal

سال: 2010

ISSN: 1876-214X

DOI: 10.2174/1876214x01003010040